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Yep - 40 psi in my road tires as well, helps a lot with handling on our twisty mountain roads, may yield a marginal increase in fuel mileage. 45 psi in the spare as does RTexasF.
I strongly believe that's just placebo thinking. I trust all the car manufacturers engines when they put 32-35psi on those labels, and not the max those tires can handle. One can increase the pressure if the car is loaded more, but most of the time they drive just with one driver.

Higher pressure makes the contact patch smaller, so that's less grip - in turns or braking.
Also, when it hits high-frequency bumps (like small cracks in the road, expansion joints, etc), instead of absorbing the shock energy, it just provides a jarring, instant, reaction force, that diminishes further the rubber contact pressure with the asphalt. If you want the wheel "jumps" instead of staying compliant on the same path.
With high pressure, when I hit those joints in a turn (highway cloverleafs), at my relative high speed (high lateral g), I can feel the car "sliding" sideways when bouncing off those cracks. Shocks can take care only on low-frequency bumps, cannot react that fast.
In final, those jarring forces are transmitted to the suspension components (instead of being absorbed by the air and tire wall rubber), and usually the rubber bushings take the blunt. I can't imagine that being good for them.

Anyway... more power to you.
 
Replacing them one by one ends up costing more. The batteries last 10 years, if that 2004 Sienna didn't complain, probably the reader doesn't work (and they are all dead). Someone posted how to invalidate the reader with just a jumper, so it's possible to be done.

Toyota OE sensors $99/4pcs:
Non OE sensors $61/4pcs
 
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