You could use the 12 volt battery in your Prime to "jump" another Toyota Hybrid, but NOTHING ELSE. The reason for this is because Toyota Hybrids only need about 1000 watts of power (83 amps) for the first couple of seconds to start up the brake booster pump, the power steering booster, and the various computers and instrument panel lights. After this start-up surge is completed, the power needed by the computers is about 42 amps (500 watts). Once the computers boot up, which takes no more than 5 seconds total, the traction battery will supply 12 volt power via the DC converter, recharging the week or dead 12 volt battery and you can disconnect the jumper cables.
But if the car needing a jump start is, say, a "regular" Toyota ICE car, meaning not the Hybrid models, or any other car that's not a Toyota Hybrid, the donor car has to have a battery with enough current capacity, called "cold cranking amps" on the battery label, to supply up to 700 amps (and maybe a lot more in very cold weather) to crank the starter motor fast enough for the gas engine to start and thus to spin the alternator. The battery in your Rav4 Hybrid or Rav4 Prime isn't designed to supply 4 or 5 kilowatts of cranking power for a conventional starter motor, or even the heat pump motor, which is a 3-phase synchronous motor which is powered from the traction battery through the a/c Inverter.
Another thing to keep in mind is that the electrical system in your Rav4 Prime is connected to about a dozen different computers, each of which is extremely sensitive to voltage surges. Jump starting another car off of the 12 volt battery in your Rav4 exposes your car to the risk of a "kick-back" voltage surge from the other car that could damage some very expensive components in your Rav. It's really not recommended by Toyota to jump start other cars off of any of their Hybrid models, and ultimately, you simply can't jump start a conventional ICE car anyway because the puny batteries in Toyota Hybrids aren't powerful enough to crank a 12 volt engine starter motor.
If it's YOUR OWN Rav4 Prime that has the dead battery, and you need to jump start your car from someone else's, you can do so if you are careful and follow this procedure:
1. First you have to get into your car. If it's locked and the battery is dead and the windows are all rolled up, you use the emergency mechanical key that's part of your fob to unlock the driver's door. You should practice this procedure so that you will know what to do in an actual dead battery situation. You will need light-duty (8 gauge or 10 gauge) jumper cables, 20 foot long ones are usually sufficient. Buy a set and store them under the driver's seat, or somewhere that you can get at them easily (
NOT in the spare tire well! You can't open the rear hatch if the battery is dead!)
2.
CRITICALLY IMPORTANT! The engine in the donor car MUST NOT be running! If it is, turn it off and remove the key from the ignition so that no one can start the car by mistake. The reason for having the donor car's engine not running, is that you don't want to risk a voltage surge traveling through the jumper cables between the two cars, and there's a substantial risk of this if the donor car's engine is running. A voltage surge could damage computers in your car.
3. Once you have unlocked the driver's door with the emergency mechanical key, open the hood. You won't be able to open the rear hatch yet since there's no way to unlock it short of crawling back there and popping it open with the emergency mechanical latch button.4. On the driver's side of the engine bay, there's a fuse box. Pop this open and locate the emergency jump start terminal. It has a plastic flip-up cover to insulate it. Flip the cover open, and attach the red jumper cable between it and the red (positive +) terminal of the donor battery. This photo is from a Rav4 Hybrid; the Prime has the same terminal.
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5. Over toward the left side of the engine, there's a hunk of aluminum sticking out towards the front of the car that looks like a handgrip. This is where you attach the Black jumper cable to the Negative (-) terminal of the donor battery. Remember that in modern cars, the electrical system is Negative Ground, meaning that the engine block, the car's steel body panels, and the various framing and suspension pieces are all electrically connected to the Negative battery terminal.
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6. Once the two jumper cables are connected, double check that the engine in the donor car isn't running, then get into your Rav, and start it the usual way (press on the brake pedal and push the power button). If the battery in your key fob is weak, the car might have trouble sensing it, in which you might need to take a moment here to replace the fob battery, too.
7. Once the READY light on your instrument panel is lit, it means that that power is flowing from your traction battery to re-charge the 12 volt battery, and you can disconnect and stow the jumper cables. NOTE: Let the car idle in READY mode for at least 30~45 minutes, or drive it somewhere for that long, to allow the 12 volt battery to recharge.
8. Clearing Trouble Codes. Here's where you might want to invest $40 in an OBD-II bluetooth scan tool, and install the Car Scanner app on your phone. When your 12 volt battery goes dead in a 2023 Rav4 Hybrid or Prime, the Check Engine Warning Light will be lit after you jump start the car, and there will be 3 or 4 trouble codes stored in the Engine Control Unit. This is ridiculous, and I can't imagine why Toyota would ever think that just because the 12 volt battery went flat, that a trouble code needed to be generated. But the fact remains that you will either have to ignore that warning light on the dash, or go to a mechanic/dealership to get it cleared, or clear it yourself with an OBD-II scan tool. Dead batteries in Toyota Hybrids happen often enough that, in my opinion, Toyota should give owners a scan tool with the car, same as they give you a key fob. BTW, I'm still waiting on my second fob, too. Grrrrrr!
NOTE: On my 2023 Rav4 Prime, I have had the 12 volt battery go dead on me 3 times in just the first 3 months of ownership, due to leaving a Dome light on, or leaving an OBD-II scanner plugged in overnight. There is supposed to be a timer that turns off the dome lights after 30 minutes, but I think there are certain circumstances wherein this timer gets bypassed and the dome light in the cargo bay won't automatically turn off. Also, the emergency flashers will never automatically turn off, and it looks like at least some models of OBD-II scanners don't have auto-off timers. Anyway, everybody who owns a Toyota Hybrid needs to carry jumper cables and know how to jump start their car. I had to do this a half-dozen times in my 2029 Prius Prime in the 4 years I owned it. The 12 volt batteries in these Hybrids are tiny, and they just have no reserve capacity. I killed the battery in my Prius once just by having the car's radio playing for a couple of hours in Accessory Mode one afternoon while I was working on the car.